Syncing Passwords for Multiple PC Computers

We purchased a family license under the impression that we'd be able to add passwords to one computer and then have it reflected on the other computer as well without having to continuously sync it. I enabled the "Move to Dropbox" option in preferences on both computers, but I assume I'm missing a step after that as it's not syncing. I am also not able to find a 1password file in Dropbox when I search my Dropbox folder. Any idea what I'm missing?

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